∵△ABC≌△ADE,∴∠B=∠D,∠BAC=∠DAE,又∠BAD=∠BAC-∠CAD,∠CAE=∠DAE-∠CAD,∴∠BAD=∠CAE,∵∠DAC=60°,∠BAE=100°,∴∠BAD= 1 2 (∠BAE-∠DAC)= 1 2 (100°-60°)=20°,在△ABG和△FDG中,∵∠B=∠D,∠AGB=∠FGD,∴∠DFB=∠BAD=20°.故选B.