由an+2=an+1+an,得an+3=an+2+an+1=2an+1+an,即当n=2时a5=2a3+a2,当n=1时,a3=a2+a1,即a2=a3-a1,两式联立得a5=2a3+a2=2a3+a3-a1,∵a1=1,a5=8,∴8=3a3-1,即a3=3,故选:C